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Near-infrared emissions and quantum efficiencies in Tm3+ -doped heavy metal gallate glasses for S-and U-band amplifiers and 1.8 μm infrared laser

Identifieur interne : 001370 ( Main/Exploration ); précédent : 001369; suivant : 001371

Near-infrared emissions and quantum efficiencies in Tm3+ -doped heavy metal gallate glasses for S-and U-band amplifiers and 1.8 μm infrared laser

Auteurs : H. Lin [République populaire de Chine] ; X. Y. Wang [République populaire de Chine] ; C. M. Li [République populaire de Chine] ; H. X. Yang [République populaire de Chine] ; E. Y. B. Pun [Hong Kong] ; S. Tanabe [Japon]

Source :

RBID : Pascal:07-0446618

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English descriptors

Abstract

Intense 1.8 μm and efficient 1.48 μm infrared emissions have been recorded in Tm3+ -doped alkali-barium-bismuth-gallate (LKBBG) glasses with low phonon energies under the excitation of 792 nm diode laser. The maximum emission cross-sections for 1.8 and 1.48 μm emission bands are derived to be 6.26 x 10-21 and 3.34 x 10-21 cm2, respectively, and the peak values are much higher than those in Tm3+ -doped ZBLAN glass. In low-concentration doping, the full-widths at half-maximum (FWHMs) of the two emission bands are 223 and 122 nm, and the quantum efficiencies of the 3F4 and 3H4 levels are proved to be ∼100% and 86%, respectively. When the doping concentration increases to 1 wt%, the quantum efficiency of the 3H4 level is reduced to 60% due to the cross-relaxation processes in high-concentration doping. Efficient 1.8 μm infrared emission in Er3+/Tm3+-codoped LKBBG glass has also been achieved under the excitation of 970 nm diode laser, and the probability and the efficiency of non-radiative energy transfer from Er3+ to Tm3+ are as high as 354 s-1 and 58.4%, respectively. Efficient and broad 1.8 and 1.48 μm infrared emission bands indicate that Tm3+ -doped LKBBG glasses are suitable materials in developing S- and U-band amplifiers and 1.8 μm infrared laser.


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Le document en format XML

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<title xml:lang="en" level="a">Near-infrared emissions and quantum efficiencies in Tm
<sup>3+</sup>
-doped heavy metal gallate glasses for S-and U-band amplifiers and 1.8 μm infrared laser</title>
<author>
<name sortKey="Lin, H" sort="Lin, H" uniqKey="Lin H" first="H." last="Lin">H. Lin</name>
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<term>Codoping</term>
<term>Cross relaxation</term>
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<term>Energy transfer</term>
<term>Erbium additions</term>
<term>Excitation spectrum</term>
<term>Gallates</term>
<term>Glass</term>
<term>Impurity density</term>
<term>Line widths</term>
<term>Near infrared radiation</term>
<term>Optical materials</term>
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<term>Largeur raie</term>
<term>Photoluminescence</term>
<term>Concentration impureté</term>
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<term>Spectre excitation</term>
<term>Transfert radiatif</term>
<term>Transfert énergie</term>
<term>Codopage</term>
<term>Addition erbium</term>
<term>Gallate</term>
<term>Verre</term>
<term>Matériau optique</term>
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<front>
<div type="abstract" xml:lang="en">Intense 1.8 μm and efficient 1.48 μm infrared emissions have been recorded in Tm
<sup>3+</sup>
-doped alkali-barium-bismuth-gallate (LKBBG) glasses with low phonon energies under the excitation of 792 nm diode laser. The maximum emission cross-sections for 1.8 and 1.48 μm emission bands are derived to be 6.26 x 10
<sup>-21</sup>
and 3.34 x 10
<sup>-21</sup>
cm
<sup>2</sup>
, respectively, and the peak values are much higher than those in Tm
<sup>3+</sup>
-doped ZBLAN glass. In low-concentration doping, the full-widths at half-maximum (FWHMs) of the two emission bands are 223 and 122 nm, and the quantum efficiencies of the
<sup>3</sup>
F
<sub>4</sub>
and
<sup>3</sup>
H
<sub>4</sub>
levels are proved to be ∼100% and 86%, respectively. When the doping concentration increases to 1 wt%, the quantum efficiency of the
<sup>3</sup>
H
<sub>4</sub>
level is reduced to 60% due to the cross-relaxation processes in high-concentration doping. Efficient 1.8 μm infrared emission in Er
<sup>3+</sup>
/Tm
<sup>3+</sup>
-codoped LKBBG glass has also been achieved under the excitation of 970 nm diode laser, and the probability and the efficiency of non-radiative energy transfer from Er
<sup>3+</sup>
to Tm
<sup>3+</sup>
are as high as 354 s
<sup>-1</sup>
and 58.4%, respectively. Efficient and broad 1.8 and 1.48 μm infrared emission bands indicate that Tm
<sup>3+</sup>
-doped LKBBG glasses are suitable materials in developing S- and U-band amplifiers and 1.8 μm infrared laser.</div>
</front>
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